李佳敏, 高阳, 江世雄, 翁孙贤, 吴水平. 变电站典型可燃物燃烧释放烟尘粒径分布、微观形貌与水溶性离子组成研究[J]. 职业卫生与应急救援, 2023, 41(3): 359-365. DOI: 10.16369/j.oher.issn.1007-1326.2023.03.020
引用本文: 李佳敏, 高阳, 江世雄, 翁孙贤, 吴水平. 变电站典型可燃物燃烧释放烟尘粒径分布、微观形貌与水溶性离子组成研究[J]. 职业卫生与应急救援, 2023, 41(3): 359-365. DOI: 10.16369/j.oher.issn.1007-1326.2023.03.020
LI Jiamin, GAO Yang, JIANG Shixiong, WENG Sunxian, WU Shuiping. Study on particle size distribution, microstructure, and water-soluble ion composition of smoke released by typical combustibles in substations[J]. Occupational Health and Emergency Rescue, 2023, 41(3): 359-365. DOI: 10.16369/j.oher.issn.1007-1326.2023.03.020
Citation: LI Jiamin, GAO Yang, JIANG Shixiong, WENG Sunxian, WU Shuiping. Study on particle size distribution, microstructure, and water-soluble ion composition of smoke released by typical combustibles in substations[J]. Occupational Health and Emergency Rescue, 2023, 41(3): 359-365. DOI: 10.16369/j.oher.issn.1007-1326.2023.03.020

变电站典型可燃物燃烧释放烟尘粒径分布、微观形貌与水溶性离子组成研究

Study on particle size distribution, microstructure, and water-soluble ion composition of smoke released by typical combustibles in substations

  • 摘要:
      目的  开展可燃物燃烧烟尘颗粒的粒径分布、微观形貌与组成特征研究,全面了解火灾烟尘信息。
      方法  收集变电站火灾燃烧现场的电缆外护套、橡胶轮胎、电线绝缘层、绝缘纸板、变压器油和火灾残留油,通过燃烧模拟实验,采用颗粒物分级采样器收集燃烧释放的烟尘颗粒,分析不同烟尘的粒径分布特征及其在人体呼吸道不同沉积部位的分布情况。通过对比不同粒径烟尘的扫描电镜图像,了解不同粒级颗粒的微观形貌与典型粒子的元素组成。
      结果  基于离子色谱分析,Cl-排放因子为0.089 2 ~ 1.207 2 μg/g,占水溶性离子的57.3% ~ 67.9%,且与其粒径分布特征在固、液燃烧物之间存在不同。
      结论  不同的燃烧物释放的烟尘均以粒径<0.25 μm的颗粒为主,且Cl-排放因子存在差异,这些差异可作为烟尘来源及火灾现场人群呼吸暴露评价的依据。

     

    Abstract:
      Objective  To carry out research on the particle size distribution, micro-morphology, and composition characteristics of combustible combustion smoke particles, and comprehensively understand the smoke information of fires.
      Methods  The cable outer sheath, rubber tires, wire insulation layer, insulating cardboard, transformer oil, and fire residue oil at the combustion site of the substation fire were collected. Through combustion simulation experiments, use a particle matter classification sampler to collect the smoke particles released by combustion and analyze the particle size distribution characteristics of different smoke particles and their distribution in different deposition sites of the human respiratory tract. By comparing the scanning electron microscope images of different particle sizes of smoke dust, the micro-morphology and elemental composition of different particle sizes were surveyed.
      Results  Based on ion chromatography analysis, Cl-emission factor was 0.089 2-1.207 2 μg/g, accounting for 57.3%-67.9% of water-soluble ions, and there were differences in its particle size distribution characteristics between solid and liquid combustibles.
      Conclusions  The smoke particles released by different combustibles were mainly particles with a diameter less than 0.25 μm, and there were differences in Cl-emission factors. These differences could be used as the basis for evaluating the source of smoke dust and respiratory exposure assessment of personnel at fire scenes.

     

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