浦征宇, 林占祥, 马盼. 锂电池热失控后气体爆炸下限影响因素研究[J]. 职业卫生与应急救援, 2024, 42(6): 798-801, 811. DOI: 10.16369/j.oher.issn.1007-1326.2024.06.019
引用本文: 浦征宇, 林占祥, 马盼. 锂电池热失控后气体爆炸下限影响因素研究[J]. 职业卫生与应急救援, 2024, 42(6): 798-801, 811. DOI: 10.16369/j.oher.issn.1007-1326.2024.06.019
PU Zhengyu, LIN Zhanxiang, MA Pan. Study on the factors affecting the lower explosive limit of gas after thermal runaway of lithium battery[J]. Occupational Health and Emergency Rescue, 2024, 42(6): 798-801, 811. DOI: 10.16369/j.oher.issn.1007-1326.2024.06.019
Citation: PU Zhengyu, LIN Zhanxiang, MA Pan. Study on the factors affecting the lower explosive limit of gas after thermal runaway of lithium battery[J]. Occupational Health and Emergency Rescue, 2024, 42(6): 798-801, 811. DOI: 10.16369/j.oher.issn.1007-1326.2024.06.019

锂电池热失控后气体爆炸下限影响因素研究

Study on the factors affecting the lower explosive limit of gas after thermal runaway of lithium battery

  • 摘要:
    目的 分析锂电池热失控后产生气体的爆炸危险性,探究气体爆炸下限与其影响因素之间的关系,为完善锂电池电化学储能技术的安全管理提供科学依据。
    方法 通过分析锂电池热失控后气体爆炸下限的影响因素,针对锂电池热失控后产生气体中氢气体积分数与温度两个关键性因素进行实验研究,分析爆炸下限与影响因素之间的关联性。
    结果 锂电池热失控气体氢气体积分数范围在40%~75%时,其爆炸下限随着氢气体积分数的升高逐渐从6.6%降至4.8%,氢气体积分数与爆炸下限值的线性关系的特征曲线为y =-0.051 x + 8.612,相关系数为0.998。含体积分数约50%氢气的气体样品,在30~250℃下,爆炸下限随着温度的升高逐渐从6.0%降至3.6%,特征曲线为y =-0.000 06 x2 + 0.008 x +5.805,相关系数为0.969。
    结论 随着氢气体积分数的升高或者温度的上升,锂电池热失控后产生气体的爆炸下限均呈现下降趋势,其间具有良好的线性关系,故可以通过氢气体积分数或温度数据预估爆炸下限。

     

    Abstract:
    Objective To analyze the explosion hazard of gases produced after the thermal runaway of lithium batteries and to explore the relationship between the lower explosive limit of gases and influencing factors, thereby establishing a research foundation for improving the safety management of lithium battery electrochemical energy storage technology.mental study was conducted on the two key factors of hydrogen concentration and temperature in the gases produced after thermal runaway. The correlation between the lower explosive limit and influencing factors was analyzed.
    Methods By analyzing the influencing factors of the lower explosive limit of gases after lithium battery thermal runaway,an experimental study was conducted on the two key factors of hydrogen concentration and temperature in the gases produced after thermal runaway. The correlation between the lower explosive limit and influencing factors was analyzed.
    Results When the hydrogen concentration in the gases produced after lithium battery thermal runaway ranged from approximately 40% to 75%, the lower explosive limit gradually decreased from 6.6% to 4.8% as the hydrogen concentration increased. The linear relationship between hydrogen concentration and the lower explosive limit was characterized by the equation y = -0.051 x + 8.612, with a correlation coefficient of 0.998. For gas samples with a hydrogen concentration of about 50%, the lower explosive limit gradually decreased from 6.0% to 3.6% as the temperature rose from 30 ℃ to 250 ℃. The characteristic curve was y = -0.000 06 x2 + 0.008 x + 5.805, with a correlation coefficient of 0.969.
    Conclusions As the hydrogen concentration increased or the temperature rose, the lower explosive limit of gases produced after lithium battery thermal runaway showed a decreasing trend, displaying a good linear relationship. The lower explosive limit could be predicted through hydrogen concentration and temperature data.

     

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