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WU Jian, LI Xiao-juan, ZHOU Chang-mei, ZHU Bao-li. Determination of hexamethylene diisocyanate in polyurethane coatings by gas chromatography with capillary column[J]. Occupational Health and Emergency Rescue, 2014, 32(4): 229-230,236.
Citation: WU Jian, LI Xiao-juan, ZHOU Chang-mei, ZHU Bao-li. Determination of hexamethylene diisocyanate in polyurethane coatings by gas chromatography with capillary column[J]. Occupational Health and Emergency Rescue, 2014, 32(4): 229-230,236.

Determination of hexamethylene diisocyanate in polyurethane coatings by gas chromatography with capillary column

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  • Received Date: June 10, 2014
  • Revised Date: July 24, 2014
  • Objective To establish the method for determination of free hexamethylene diisocyanate(HDI) in polyurethane coatings by gas chromatography. Methods Two kinds of polyurethane coatings are analyzed by gas chromatography with hydrogen flame ionization detector and the DB-17 column. Results There was a good linear relationship of this established method in the range 0.52 to 520 μg/mL. The detection limit was 0.52 μg/mL and the lowest detection concentration was 5 mg/kg(1 g taken sample). The RSD was less than 5% and the recovery rate reached 80% or more. Conclusion The experimental results showed that this method can be used to determine free hexamethylene diisocyanate content in polyurethane coatings.
  • [1]
    钱伯章. 世界聚氨酯及其原料工业的现状及进展[J]. 国际化工信息,2002(5):1-3.
    [2]
    李涛,张敏,王丹,等. 日本化学物质推荐性容许浓度(2007年度)[J]. 国外医学卫生学分册,2009,36(6):321-327.
    [3]
    中华人民共和国卫生部. GBZ 2.1-2007工作场所有害因素职业接触限值第1部分:化学有害因素[S]. 北京:人民卫生出版社,2010.
    [4]
    Neubauer N R,Skreckoski G R,White R G,et al. Gas chromatographic determination of free toluene diisocyanate in adducts with trimethylolpropane[J]. Anal Chem,1963,35(11):1647-1649.
    [5]
    孙少华. 聚氨酯涂料中游离甲苯二异氰酸酯的气相色谱分析[J]. 涂料工业,1995(5):36-38.
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